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THERMAL PHYSICS

Thermodynamic Process and 1st Law of Thermodynamics

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Слайд 1THERMAL PHYSICS

THERMAL PHYSICS

Слайд 2Thermodynamic Process and 1st Law of Thermodynamics

Thermodynamic Process and 1st Law of Thermodynamics

Слайд 3Learning Objectives
understand and describe principles of work of heat engines
recall

and apply

Learning Objectivesunderstand and describe principles of work of heat enginesrecall and apply

Слайд 42nd Law of Thermodynamics
There are many processes in thermodynamics that

are consistent with the first law but are nonetheless impossible.

2nd Law of ThermodynamicsThere are many processes in thermodynamics that are consistent with the first law but

Слайд 52nd Law of Thermodynamics

2nd Law of Thermodynamics

Слайд 62nd Law of Thermodynamics
If you put a layer of salt

in a jar and cover it with a layer of

similar-sized grains of pepper, when you shake it you get a thorough mixture. But no matter how long you shake it, the mixture does not separate into layers again.
2nd Law of ThermodynamicsIf you put a layer of salt in a jar and cover it with

Слайд 72nd Law of Thermodynamics
Coffee cups and glasses break spontaneously if

you drop them. But they don’t go back together spontaneously.
The

spontaneous (without the action of another agent) transfer of thermal energy from a cold body to hotter body


2nd Law of ThermodynamicsCoffee cups and glasses break spontaneously if you drop them. But they don’t go

Слайд 82nd Law of Thermodynamics
The air in a room suddenly occupying

just one half of the room and leaving the other

half empty.
A glass of water at room temperature suddenly freezing, causing the temperature of the room to rise

2nd Law of ThermodynamicsThe air in a room suddenly occupying just one half of the room and

Слайд 92nd Law of Thermodynamics
These processes do not open happen because

they are forbidden by a very special law of physics

– the second law of thermodynamics.
2nd Law of ThermodynamicsThese processes do not open happen because they are forbidden by a very special

Слайд 102nd Law of Thermodynamics
The 1st law of thermodynamics (conservation of

energy) would not be violated any of these processes.
To explain

this lack of reversibility, scientists in the latter half of the 19th century formulated a new principle known as the 2nd law of thermodynamics.
2nd Law of ThermodynamicsThe 1st law of thermodynamics (conservation of energy) would not be violated any of

Слайд 112nd Law of Thermodynamics
The second law of thermodynamics describes the

directionality of natural thermodynamic processes.
It can be stated in several

equivalent forms.
2nd Law of ThermodynamicsThe second law of thermodynamics describes the directionality of natural thermodynamic processes.It can be

Слайд 122nd Law of Thermodynamics
According to Rudolf J.E. Clausius (1822 –

1888)
“heat can flow spontaneously from a hot object to a

cold object ; heat will not flow spontaneously from a cold object to a hot object”
2nd Law of ThermodynamicsAccording to Rudolf J.E. Clausius (1822 – 1888)“heat can flow spontaneously from a hot

Слайд 132nd Law of Thermodynamics
The engine statement is that “no cyclic

process can convert heat completely into work”.

2nd Law of ThermodynamicsThe engine statement is that “no cyclic process can convert heat completely into work”.

Слайд 142nd Law of Thermodynamics
The refrigerator statement is that “no cyclic

process can transfer heat from a colder place to a

hotter place with no input of mechanical work”.
2nd Law of ThermodynamicsThe refrigerator statement is that “no cyclic process can transfer heat from a colder

Слайд 152nd Law of Thermodynamics
The development of a general statement of

the second law of thermodynamics was based partly on the

study of heat engines.
2nd Law of ThermodynamicsThe development of a general statement of the second law of thermodynamics was based

Слайд 162nd Law of Thermodynamics
A heat engine is any device that

changes thermal energy into mechanical work, such as steam engines

and automobile engines.
2nd Law of ThermodynamicsA heat engine is any device that changes thermal energy into mechanical work, such

Слайд 172nd Law of Thermodynamics
The second law of thermodynamics can also

be stated in terms of the concept of entropy, a

quantitative measure of the degree of disorder or randomness of a system.
2nd Law of ThermodynamicsThe second law of thermodynamics can also be stated in terms of the concept

Слайд 182nd Law of Thermodynamics
The 2nd law tells us that as

the time moves forward, the disorder in the universe increases.

2nd Law of ThermodynamicsThe 2nd law tells us that as the time moves forward, the disorder in

Слайд 192nd Law of Thermodynamics

2nd Law of Thermodynamics

Слайд 202nd Law of Thermodynamics

2nd Law of Thermodynamics

Слайд 21Reversible and Irreversible Process
Thermodynamic processes that occur in nature are

all irreversible process. These are processes that proceed spontaneously in

one direction but not the other.
Reversible and Irreversible ProcessThermodynamic processes that occur in nature are all irreversible process. These are processes that

Слайд 22Reversible and Irreversible Process
The flow of heat from a hot

body to a cooler body is irreversible.
Sliding a book across

a table converts mechanical energy into heat by friction; this is irreversible, for no one has ever observe the reverse process.
Reversible and Irreversible ProcessThe flow of heat from a hot body to a cooler body is irreversible.Sliding

Слайд 23Reversible and Irreversible Process
A system that undergoes an “idealized” reversible

process is always very close to being in thermodynamic equilibrium

within itself and with its surroundings.
Reversible and Irreversible ProcessA system that undergoes an “idealized” reversible process is always very close to being

Слайд 24Reversible and Irreversible Process
Reversible processes are thus equilibrium processes, with

the system always in thermodynamic equilibrium.
A reversible process is an

idealization that can never be precisely attained in real world.
Reversible and Irreversible ProcessReversible processes are thus equilibrium processes, with the system always in thermodynamic equilibrium.A reversible

Слайд 25Reversible and Irreversible Process

Reversible and Irreversible Process

Слайд 26Reversible and Irreversible Process

Reversible and Irreversible Process

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