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Interest in the synthesis of metal nanoparticles by explosion

Factors Affecting Particle SizesExplosiveType of metalMetal concentrationCarbon supplements

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Слайд 1 Interest in the synthesis of metal nanoparticles by explosion
Ten

and silver stearate 3-20 nm
Silver Azide 80 nm
Ferrocene and picric

acid 5-20 nm
Hexogen and iron nitrate 18-55 nm
Ten and cobalt nitrate 15-25 nm
Ten and nickel nitrate 10-20 nm





Interest in the synthesis of metal nanoparticles by explosion Ten and silver stearate 3-20 nmSilver Azide

Слайд 2Factors Affecting Particle Sizes
Explosive
Type of metal
Metal concentration
Carbon supplements

Factors Affecting Particle SizesExplosiveType of metalMetal concentrationCarbon supplements

Слайд 3Formulation of the problem
The composition of explosives and metal (palladium)

are fixed; there are no additional carbon additives
Determination of the

empirical dependence of particle sizes on the type of chemical compound palladium
Formulation of the problemThe composition of explosives and metal (palladium) are fixed; there are no additional carbon

Слайд 4Used compounds and explosives
4 palladium compounds (3% wt.) 1) Palladium nitrate

Pd (NO3)2
2) Palladium Acetate Pd(CO3 COO)2
3) Caprylate Palladium

Pd (C7 H15 COO)2
4) Palladium stearate Pd (C17 H35 COO)2
Explosive composition - TATB / HMX 50/50
Used compounds and explosives4 palladium compounds (3% wt.)	1) Palladium nitrate Pd (NO3)2 	2) Palladium Acetate Pd(CO3 COO)2

Слайд 5Preparing and conducting an experiment
Mixing a solution of a metal

precursor with TATB powder
Evaporation
Octogen Blending
The placement of a charge

in an ice shell in a previously cleaned blast chamber
Explosion collection for further research

Preparing and conducting an experimentMixing a solution of a metal precursor with TATB powderEvaporationOctogen Blending The placement

Слайд 6Preparing and conducting an experiment

Preparing and conducting an experiment

Слайд 7Palladium nitrate

Palladium nitrate

Слайд 8Palladium Acetate

Palladium Acetate

Слайд 9Caprilat Palladium

Caprilat Palladium

Слайд 10Palladium stearate

Palladium stearate

Слайд 11The average linear and average mass particle sizes
The average linear

particle size

dl = ∑ di / N,
N is the number of particles
The average mass particle size
dm = ∑ di4 / ∑ di3

The average linear and average mass particle sizesThe average linear particle size

Слайд 12Particle size distribution
Nitrate Pd
dl = 6.4 nm
dm = 10.7

nm
Сm = 1.38%
Pd Acetate
dl = 3.1 nm
dm = 4.3

nm
Cm = 1.39%

Caprilat Pd
dl = 2.5 nm
dm = 2.9 nm
Cm = 0.81%

Stearate Pd
dl = 1.5 nm
dm = 1.7 nm
Cm = 0.45%

Particle size distributionNitrate Pd dl = 6.4 nmdm = 10.7 nmСm = 1.38%Pd Acetate dl = 3.1

Слайд 13Results and Conclusions
Palladium nanoparticles obtained by detonation synthesis
Particle

size is determined by the chemical composition of the palladium

precursor
The average particle size, depending on the precursor, is 1.5-6.4 nm
The results are published in the Journal of Physics: Conference Series, Volume 1147.
Detonation synthesis of non-agglomerated metallic nanoparticles deposited on carbon supports. AO Kashkarov, ER Pruuel, KA Ten, E Yu, Gerasimov, SI Kremenko, IA Rubtsov, GR Dashapilov, PA Pyrjaev and BL Moroz
Results and Conclusions Palladium nanoparticles obtained by detonation synthesis Particle size is determined by the chemical composition

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