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THERMAL PHYSICS

Learning Objectivesunderstand and apply first law of thermodynamicsdistinguish graphs of adiabatic and isothermal processesunderstand second law of thermodynamics

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Слайд 1THERMAL PHYSICS

THERMAL PHYSICS

Слайд 2Learning Objectives
understand and apply first law of thermodynamics
distinguish graphs of

adiabatic and isothermal processes
understand second law of thermodynamics

Learning Objectivesunderstand and apply first law of thermodynamicsdistinguish graphs of adiabatic and isothermal processesunderstand second law of

Слайд 3Terms to Remember!
Thermodynamics
Thermodynamic System
Surroundings
Heat
Work
Internal Energy

Terms to Remember!ThermodynamicsThermodynamic SystemSurroundingsHeatWorkInternal Energy

Слайд 4Thermodynamics
Thermodynamics is the macroscopic study of the behaviour of systems.

It was a mathematical theory developed before a detailed understanding

of the particulate nature of gases.
ThermodynamicsThermodynamics is the macroscopic study of the behaviour of systems. It was a mathematical theory developed before

Слайд 5Thermodynamic System
Thermodynamic System is a macroscopic aspect of a problem

than can be considered as a separate whole. An ideal

gas for example can have energy flowing in or out of it from
the surroundings.
Thermodynamic SystemThermodynamic System is a macroscopic aspect of a problem than can be considered as a separate

Слайд 6Surroundings
Surroundings is everything in the problem outside the
thermodynamic system.

Heat can flow from the system to the surroundings and

vice versa.
SurroundingsSurroundings is everything in the problem outside the thermodynamic system. Heat can flow from the system to

Слайд 7Surroundings

Surroundings

Слайд 8Thermodynamic Systems

Thermodynamic Systems

Слайд 9Isolated System

Isolated System

Слайд 10Closed System

Closed System

Слайд 11Open System

Open System

Слайд 12Heat
Heat (Q) is an amount of thermal energy transferred from

the surroundings to an ideal gas. It is a result

of a temperature difference.
HeatHeat (Q) is an amount of thermal energy transferred from the surroundings to an ideal gas. It

Слайд 13Heat Flow (Review)

Heat Flow (Review)

Слайд 14Work
Work (W) is simply a macroscopic transfer of energy from

the gas to the surroundings.

WorkWork (W) is simply a macroscopic transfer of energy from the gas to the surroundings.

Слайд 21Change in Internal Energy
Change in Internal Energy (∆U) is the

change in a gas’ energy due to the PE and

KE of the molecules.
It does not include external factors such as gravity.
∆U for an ideal gas will involve temperature changes (∆θ).
Change in Internal EnergyChange in Internal Energy (∆U) is the change in a gas’ energy due to

Слайд 22Change in Internal Energy
The change in internal energy (ΔU) of

a closed system will be equal to the energy added

to the system by heating minus the work done by the system on the surroundings.
ΔU = Q – W
Change in Internal EnergyThe change in internal energy (ΔU) of a closed system will be equal to

Слайд 231st Law of Thermodynamics
The First Law of Thermodynamics states that

when heat Q is added to a system while the

system does work W, the internal energy U changes by an amount equal to Q – W.
ΔU = Q – W
1st Law of ThermodynamicsThe First Law of Thermodynamics states that when heat Q is added to a

Слайд 241st Law of Thermodynamics
Since Q and W represent energy transferred

into or out of the system , the internal energy

changes accordingly.
The First Law of Thermodynamics is great and broad statement of the law of conservation of energy.
1st Law of ThermodynamicsSince Q and W represent energy transferred into or out of the system ,

Слайд 251st Law of Thermodynamics
The internal energy of any thermodynamic system

depends only on its state. The change in internal energy

in any process depends only on the initial and final states, not on the path.
The internal energy of an isolated system is constant.
1st Law of ThermodynamicsThe internal energy of any thermodynamic system depends only on its state. The change

Слайд 26State
State is defined as the physical condition of the system.

StateState is defined as the physical condition of the system.

Слайд 27Important Note
A given system at any moment is in particular

state and can be said to have a certain amount

of internal energy.
But a system does NOT have a certain amount of heat or work.
Important NoteA given system at any moment is in particular state and can be said to have

Слайд 28Important Note
Rather, when work is done on a system or

when heat is added or removed from a system, the

state of the system changes.
Important NoteRather, when work is done on a system or when heat is added or removed from

Слайд 29Important Note
Thus, work and heat are involved in thermodynamic processes

that can change the system from one state to another;

they are not characteristic of the state itself.
Important NoteThus, work and heat are involved in thermodynamic processes that can change the system from one

Слайд 30State Variables
Quantities which describe the state of the system is

called state variables.
Internal Energy (U) Mass (m)
Pressure (P) Volume (V)
Temperature (T)


Number of Moles (n)
State VariablesQuantities which describe the state of the system is called state variables.Internal Energy (U)		 Mass (m)Pressure

Слайд 31Sample Problem
2500 J of heat is added to a system,

and 1800 J of work is done on the system.

What is the change in internal energy of the system?
Sample Problem2500 J of heat is added to a system, and 1800 J of work is done

Слайд 32Sample Problem
2500 J of heat is added to a system,

and 1800 J of work is done by the system.

What is the change in internal energy of the system?
Sample Problem2500 J of heat is added to a system, and 1800 J of work is done

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