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Ferroelectrics: Historical Introduction

Ferroelectricity= reversible spontaneous polarizationAsymmetric crystal structure is required!

Слайды и текст этой презентации

Слайд 1Ferroelectrics: Historical Introduction
by Fedor Tikhonenko

Ferroelectrics: Historical Introductionby Fedor Tikhonenko

Слайд 2Ferroelectricity
= reversible spontaneous polarization
Asymmetric crystal structure is required!

Ferroelectricity= reversible spontaneous polarizationAsymmetric crystal structure is required!

Слайд 3Ferroelectricity
= reversible spontaneous polarization

Ferroelectricity= reversible spontaneous polarization

Слайд 4Ferroelectric materials
Typical ferroelectrics are complicated ceramic compounds of transition metals

( titanates, niobates, tantalates, etc.)
NO IRON!
All FE materials are also

pyroelectrics and piezoelectrics
Ferroelectric materialsTypical ferroelectrics are complicated ceramic compounds of transition metals ( titanates, niobates, tantalates, etc.)NO IRON!All FE

Слайд 5Early years (1920-1930)
FE effect first discovered in Rochelle salt by

Valasek (1920)
Materials: Single crystalls (Rochelle salt, ADP, KDP)
Methods: Solution growth
Applications:

Photo pickup
Early years (1920-1930)FE effect first discovered in Rochelle salt by Valasek (1920)Materials: Single crystalls (Rochelle salt, ADP,

Слайд 6Discrete elements (1940-1960)
Materials: ceramics (BT, PZT, LT, SBN, etc.)
Methods: casting,

pressing, evaporation, sputtering
Applications: Hi-k Caps, acoustic tranducers, filters, heat detectors
1952:

PZT was synthesized in Tokyo Institute of Technology

Discrete elements (1940-1960)Materials: ceramics (BT, PZT, LT, SBN, etc.)Methods: casting, pressing, evaporation, sputteringApplications: Hi-k Caps, acoustic tranducers,

Слайд 7Hybrid microelectonics (1970-1990)
Materials: thin films (PZT, PZLT, PLT, LN,

SBN)
Methods: sol-gel, LPE, MBE, CVD, MOCVD, PECVD
Applications: MEMS, NVM, IR

sensors

Perovskite structure materials (Perovskii, 1895)

Hybrid microelectonics (1970-1990) Materials: thin films (PZT, PZLT, PLT, LN, SBN)Methods: sol-gel, LPE, MBE, CVD, MOCVD, PECVDApplications:

Слайд 8Integrated circuits (since 2000)
Materials: ultra thin films (HfO2, ZrO2)
Methods: CVD,

MOCVD, ALD
Applications: NVM, NN, IR starring arrays
Main problems: phase transitions,

FE induced/suppressed by stress and strain and influenced by surface states and defects.
Integrated circuits (since 2000)Materials: ultra thin films (HfO2, ZrO2)Methods: CVD, MOCVD, ALDApplications: NVM, NN, IR starring arraysMain

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