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"Plastics. General characteristics. Classification. Composition. The main types

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Plastics - materials, which are based on polymers which are in the period of formation of products in the viscous fluid or highly elastic, and in the operation - in the

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Слайд 1 "Plastics.
General characteristics. Classification. Composition. The main types

of plastics, their appointment. Usage in technology in the manufacture

of dental prostheses and devices "

Слайд 2Plastics - materials, which are based on polymers which are

in the period of formation of products in the viscous

fluid or highly elastic, and in the operation - in the glassy or crystalline state.
Polymers - a substance whose molecules consist of a large number of repeating units.
Plastics - materials, which are based on polymers which are in the period of formation of products

Слайд 3 The main starting materials for polymer dental materials are monomers

and oligomers (mono, I-D, tri-, tetra acrylates).

Monocrylat volatile, so

they are using in combination with high molecular weight esters, thereby reducing shrinkage of the polymer.
The main starting materials for polymer dental materials are monomers and oligomers (mono, I-D, tri-, tetra

Слайд 4 Polymerization - reaction interconnection monomer compounds with double bonds without

the formation during the reaction of any new substances.

The

reaction generated a high molecular compound that is different from the original size of a molecule.

The mechanism of the polymerization reaction is to activate some of the monomer molecules by the action of light, heat or catalysis torus and subsequently joining the already activated molecules to other molecules to form longer chains.

This connection continues as long as the energy is initially activated molecule dissipates.
Polymerization - reaction interconnection monomer compounds with double bonds without the formation during the reaction of

Слайд 5 Classification of plastics:
1. origin include:
• natural or biopolymers

(proteins, nucleic acids, natural number rubber);
• synthetic (polyethylene, polyamides,

epoxy resins).
Classification of plastics: 1. origin include: • natural or biopolymers (proteins, nucleic acids, natural number rubber);

Слайд 6 2. By nature:
• organic;
• inorganic;
• organ elemental.

2. By nature: • organic; • inorganic; • organ elemental.

Слайд 7Main, which are used for removable and fixed dentures:

base (rigid) polymers;
• elastic polymers or elastomers;
• polymer

(plastic) artificial teeth; • polymers for replacement of dental hard tissue defects, materials for fillings, pin teeth and tabs;
• polymeric materials for temporary non-removable dentures;
• facing polymers (for permanent fixed prosthesis);
• restoration polymers
Main, which are used for removable and fixed dentures: • base (rigid) polymers; • elastic polymers or

Слайд 8B) Support, which are used at different stages of the

manufacture of dentures:
• polymer impression material;
• polymer standard impression

trays;
• polymeric materials for the manufacture of individual spoons;
• plastic caps and temporary crown to protect the prepared teeth.
B) Support, which are used at different stages of the manufacture of dentures:• polymer impression material; •

Слайд 9B) Clinical
the temperature conditions of polymerization plastics are "hot" curing;



cold curing plastics ( "self-hardening", "quick-hardening").

In the presence of

"pink" plastic pigments;

“colorless" plastics; plastic different color impressions.
B) Clinicalthe temperature conditions of polymerization plastics are

Слайд 10 Physical properties of materials
Specific gravity - density of the material,

the amount of substance per unit volume and mass of

one cm3 of the body, expressed in grams.

Melting point - the temperature at which the substance passes from a solid to a liquid.

Shrinkage of the material - material volume reduction during cooling after casting.
Physical properties of materialsSpecific gravity - density of the material, the amount of substance per unit

Слайд 11Mechanical properties of materials
Durability - solid body's ability to resist

the impact of external forces seeking to deform.


Viscosity -

the ability of a material under load to stretch, lengthen.


Hardness - The ability of the solid material to enter the soft material under pressure.
Mechanical properties of materials Durability - solid body's ability to resist the impact of external forces seeking

Слайд 12 Elasticity - material property again to return to its original

state, acquiring its original shape after the termination of the

deforming force.

Plasticity - the ability to change shape and save it as a final deformation.

Fatigue of materials (metals, plastics) occurs when prolonged load, which creates tension.

Removing the friction arises from solid soft material
Elasticity - material property again to return to its original state, acquiring its original shape after

Слайд 13 KEY (CONSTRUCTION) MATERIALS
They should be harmless, solid, not collapse under

the action of an oral liquid, various nutrients, air, and

the pressure withstand chewing process during manufacture in which the prosthesis is subjected to tension, bending, distortion, temperature action.

Dentures should be a natural color, not to have an unpleasant taste and smell are also important availability and cost of material.
KEY (CONSTRUCTION) MATERIALS They should be harmless, solid, not collapse under the action of an oral

Слайд 14 The basic materials include:
Plastic


Porcelain


Artificial teeth


Metals

The basic materials include:PlasticPorcelain Artificial teethMetals

Слайд 15 The major components of this type of plastic compositions are:
1)

monomer - based plastics;

2) binder (phenol-formaldehyde resin, or other);



3) fillers (wood flour, asbestos, glass fiber);
The major components of this type of plastic compositions are: 1) monomer - based plastics; 2)

Слайд 16Compound of plastic
The main component fluids "monomer" is a methyl

ester of methacrylic acid stabilized inhibitor.
Each liquid contains a

specific modifier to the polymerization type resins and plastics to impart desired performance properties.
Compound of plasticThe main component fluids

Слайд 17Compound of plastic Filler - a substance that affects the strength,

hardness, shrinkage, thermal conductivity, resistance to aggressive media. Sometimes minimal

and organic, powdery and fibrous (silica flour, silica gels, silicates, various grades of finely ground glass).
Compound of plastic Filler - a substance that affects the strength, hardness, shrinkage, thermal conductivity, resistance to

Слайд 18Pigment - a substance imparting dental polymeric compositions and shades

of colors, imitating the tooth tissue and mucosa.
Requirements: harmlessness,

distribution uniformity, stability in maintaining the color under the influence of external factors, good optical properties.
Pigment - a substance imparting dental polymeric compositions and shades of colors, imitating the tooth tissue and

Слайд 19The catalyst - a substance that accelerates a chemical reaction.



The Initiator - a substance which when exposed to heat

or other factors (activator) decomposes into free radicals polymerization reaction beginning (benzoyl peroxide).
The catalyst - a substance that accelerates a chemical reaction. The Initiator - a substance which when

Слайд 20 Activator - an agent that causes the decomposition of the

initiator with the formation of active growth promoting radical polymer

chain and polymerization (dimethylparatoluidine, a tertiary amine).

Plasticizer - a substance that increases the ductility and elasticity of the material (dibutyl phthalate, dioctyl phthalate).
Inhibitor (retarder) - a substance that slows the chemical reactions, preventing spontaneous polymerization during transport and storage (hydroquinone, diphenylolpropane).
Activator - an agent that causes the decomposition of the initiator with the formation of active

Слайд 21Radiopaque material - barium sulphate, barium fluoride, barium and bismuth

glass. Their presence helps to detect polymer fragments with injuries

maxillofacial area and the introduction of elements of the prosthesis into the soft tissue.
Radiopaque material - barium sulphate, barium fluoride, barium and bismuth glass. Their presence helps to detect polymer

Слайд 22Radiopaque material - barium sulphate, barium fluoride, barium and bismuth

glass. Their presence helps to detect polymer fragments with injuries

maxillofacial area and the introduction of elements of the prosthesis into the soft tissue.
Radiopaque material - barium sulphate, barium fluoride, barium and bismuth glass. Their presence helps to detect polymer

Слайд 23 Basic (BASIC) CONSTRUCTION MATERIALS


The materials used for manufacturing bases removable

plate prostheses, called basic materials.

Basic (BASIC) CONSTRUCTION MATERIALSThe materials used for manufacturing bases removable plate prostheses, called basic materials.

Слайд 24The basis - the foundation of the denture: it strengthened

artificial teeth, clasps and other components of the prosthesis.

The basis - the foundation of the denture: it strengthened artificial teeth, clasps and other components of

Слайд 25 Basic materials must have the following characteristics:


1) sufficient strength and

elasticity necessary to ensure the integrity of the prosthesis without

deformation under chewing forces;

2) high bending resistance;

3) high resistance to impact;
Basic materials must have the following characteristics: 1) sufficient strength and elasticity necessary to ensure the

Слайд 264) a small specific gravity and low thermal conductivity;

5)

sufficient rigidity, low abrasion;


6) indifference to the action of

saliva and various nutrients
4) a small specific gravity and low thermal conductivity; 5) sufficient rigidity, low abrasion; 6) indifference to

Слайд 27 7) does not change color when exposed to light, air

and other environmental factors;

8) does not adversely affect oral

tissue and organism as a whole;

9) no adsorption of nutrients and microflora in the mouth.
7) does not change color when exposed to light, air and other environmental factors; 8) does

Слайд 28In addition, the base material must meet the following requirements:
1)

firmly connected with porcelain, metal, plastic;
2) are easily processed

into a product with a high accuracy and maintain the shape imparted;
3) be easy to fix;
4) well painted to imitate the natural color of the gums and teeth;
5) can be easily disinfected;
6) does not cause unpleasant taste and odorless.
In addition, the base material must meet the following requirements: 1) firmly connected with porcelain, metal, plastic;

Слайд 29 For bases used plastic prostheses following types:
acrylic;
vynilacril
modified

polystyrene;
copolymers or mixtures of appropriate plastics.

For bases used plastic prostheses following types: acrylic; vynilacril modified polystyrene; copolymers or mixtures of appropriate

Слайд 30Dental copolymers comprise 80% of all medical copolymers comprise copolymers

acrylmetacrylate - double or triple copolymers.

Dental copolymers comprise 80% of all medical copolymers comprise copolymers acrylmetacrylate - double or triple copolymers.

Слайд 31 It is now widely used acrylic plastic base
“Этакрил "


 
"Акродент"



  "Фторакс"



 

"Акронил"

It is now widely used acrylic plastic base“Этакрил

Слайд 32 Colorless plastic base
Plastic-based stabilizer purified from polymethylmethacrylate containing Tinuvin which

prevents aging of the plastic under the influence of an

aggressive environment. 
Colorless plastic base Plastic-based stabilizer purified from polymethylmethacrylate containing Tinuvin which prevents aging of the plastic

Слайд 33Colorless base plastic used for manufacturing dental prostheses bases in

cases where counter-stained basis as well as for other purposes

prosthodontics when necessary a transparent base material.
Colorless base plastic used for manufacturing dental prostheses bases in cases where counter-stained basis as well as

Слайд 34ELASTIC LINING MATERIALS
Need to improve the adhesion of the

denture to the oral mucosa, as well as combined production

of dental prostheses resulted in the appearance of soft elastic lining materials for denture base.

They are also used for the production of obturators, maxillofacial prosthetics, elastic pilots, etc.
ELASTIC LINING MATERIALS Need to improve the adhesion of the denture to the oral mucosa, as well

Слайд 35 Materials must meet the following medical and technical requirements:
1) is

firmly connected with the base material;
2) be non-toxic;
3)

to maintain the elasticity;
4) good wetting;
5) does not dissolve in the mouth;
6) have a high resistance to wear;
7) does not change color;
8) to be technologically advanced.
Materials must meet the following medical and technical requirements: 1) is firmly connected with the base

Слайд 36Indications for use 
1) with a sharp ridge atrophy of alveolar

processes when contraindicated for all the usual methods of fixation

of the prosthesis

2) in the presence of bony protrusions and ridges on the prosthetic bed, so that a solid basis for the prosthesis causes pain;

3) for the reduction of saliva in a patient worsens the fixation and stabilization of the prosthesis;

4) in the anomalous form of bite;
Indications for use 1) with a sharp ridge atrophy of alveolar processes when contraindicated for all the usual

Слайд 37Indications for use 
5) the need to create an increased adhesion

of the prosthesis (for musicians playing wind instruments);

6) to

create a new form of an old or bad adjacent denture base;

7) for manufacturing obturators;
Indications for use  5) the need to create an increased adhesion of the prosthesis (for musicians playing

Слайд 38 Resilient Lining materials for denture bases, depending on the nature

of the material is divided into four types:

acrylic
pliable
silicone based


fluorine rubber
Resilient Lining materials for denture bases, depending on the nature of the material is divided into

Слайд 39 Methods of polymerization of basic plastics
Plastics made acrylic-based - is

the main structural material for the manufacture of removable plate

dentures and orthodontic appliances.
Methods of polymerization of basic plastics Plastics made acrylic-based - is the main structural material for

Слайд 40Methods for forming plastic powder in pasty condition divided into

two types: casting and compression molding.

Methods for forming plastic powder in pasty condition divided into two types: casting and compression molding.

Слайд 41Plastics Polymerization
Polymerization - a chemical reaction in which there is

an association of molecules of the same low molecular weight

substances.

Because this reaction produces high molecular weight compounds that are similar in composition to the primary material, but it differs from the quantity and properties of molecules.
Plastics Polymerization Polymerization - a chemical reaction in which there is an association of molecules of the

Слайд 42To study the basic acrylic resin polymerization quality using three

methods:
1. Polymerization for "water bath" in the cell in a

plaster mold;
To study the basic acrylic resin polymerization quality using three methods: 1. Polymerization for

Слайд 43 2. The polymerization to dry under pressure;

2. The polymerization to dry under pressure;

Слайд 44 3. Polymerization an improved apparatus for foundry molding.

3. Polymerization an improved apparatus for foundry molding.

Слайд 45 Plastics for fixed prostheses
Most plastics used
"Sinma-M" and
"Sinma-74."

This

acrylic hot curing plastic such as "powder-liquid."

Plastics for fixed prostheses Most plastics used

Слайд 46 Artificial teeth
Sets the front teeth are divided into 17 sizes.



The main part of the headset upper

anterior teeth is made up of 3 styles: rectangular, wedge-shaped and oval.
 
Sets the lower anterior teeth are available in two styles: rectangular and wedge.

Sets of posterior teeth are available in 5 styles with increasing size. Teeth are available 7 colors.
Artificial teeth Sets the front teeth are divided into 17 sizes.   The main part

Слайд 47

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